Collect. Czech. Chem. Commun.
1991, 56, 269-276
https://doi.org/10.1135/cccc19910269
Alkoxide-to-hydroxide ion activity ratios in water-ethylene glycol and water-1-propanol systems
Jiří Mollin and Eva Karásková
Department of Inorganic and Physical Chemistry, Palacký University, 771 46 Olomouc
Abstract
The dissociation constants of water and alcohol, their ionic products as well the ionic product of the mixture, equilibrium constants of the OH- + ROH ⇆ RO- + H2O equilibrium, and the alkoxide-to-hydroxide ion activity ratios were determined in water-ethylene glycol and water-1-propanol systems. The conditions of validity of Rochester’s equation are discussed.
