Collect. Czech. Chem. Commun. 1990, 55, 1478-1484

The application of the relaxation method to the study of Fe3+, Fe2+, H2SO4/Pt electrode system

Adolf Kisza, Jerzy Każmierczak and Elżbieta Miciór

Institute of Chemistry, University of Wrocław, 50-383 Wrocław, Poland


The paper presents the application of the relaxation theory of electrode reaction in a diffusional system. The theoretical equations derived are tested by the experimental results of a simple charge transfer reaction Fe3+ + e = Fe2+ on Pt electrode in 1M H2SO4.