Collect. Czech. Chem. Commun. 1990, 55, 1143-1148

Comments on the Antonow and interfacial interaction rules

Jan Kloubek

The J. Heyrovský Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, 182 23 Prague 8


Results presented for the aliphatic hydrocarbon-water interface show that the recent hypothesis of the free energy minimization called interfacial interaction rule, which was suggested as a theoretical base of the Antonow rule, cannot be generally valid.