Collect. Czech. Chem. Commun.
1989, 54, 1257-1262
https://doi.org/10.1135/cccc19891257
Crystal structure of (E)-1,2-bis(butylsulfonyl)ethylene
Jaroslav Podlahaa, Jana Podlahováa and Jindřich Hašekb
a Department of Chemistry, Charles University, 128 40 Prague 2
b Institute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06 Prague 6
Abstract
The title compound is orthorhombic, space group Pbca, a = 8.523(1), b = 17.467(3), c = 9.449(1) Å, Z = 4, R = 0 052 for 878 observed reflections. The molecule is centrosymmetric with inversion at the middle of the double bond. The characteristic feature of the structure is an almost exactly planar O-S-C(H)=C'(H')-S'-O' moiety with the H···O' and H'···O distances of 2.55 Å, indicating much more weaker intramolecular hydrogen bonds than in the related ethylsulfonyl derivative studied earlier.
