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Collect. Czech. Chem. Commun. 1989, 54, 400-412
https://doi.org/10.1135/cccc19890400

Triterpenoid 2,3-ketols, diols and their acetates: Preparation and conformation of the ring A

Jiří Klinot, Jan Sejbal and Alois Vystrčil

Department of Organic Chemistry, Charles University, 128 40 Prague 2

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  • Zhabinskii Vladimir N, Osiyuk Darya A, Ermolovich Yuri V, Chaschina Natalia M, Dalidovich Tatsiana S, Strnad Miroslav, Khripach Vladimir A: Synthesis of ergostane-type brassinosteroids with modifications in ring A. Beilstein J. Org. Chem. 2017, 13, 2326. <https://doi.org/10.3762/bjoc.13.229>
  • Shernyukov A. V., Salakhutdinov N. F., Tolstikov G. A.: Methods of the synthesis of A-seco derivatives of pentacyclic triterpenoids. Russ Chem Bull 2013, 62, 878. <https://doi.org/10.1007/s11172-013-0120-3>
  • Trant John F., Hudlicky Tomas: Ring-opening of hindered cyclic epoxides with potassium carboxylates in the presence of conjugate acids. Can. J. Chem. 2013, 91, 1179. <https://doi.org/10.1139/cjc-2013-0386>
  • Zhu Chunsheng, Tang Pingping, Yu Biao: Total Synthesis of Lobatoside E, A Potent Antitumor Cyclic Triterpene Saponin. J. Am. Chem. Soc. 2008, 130, 5872. <https://doi.org/10.1021/ja801669r>
  • Tišlerová Iva, Richtr Václav, Klinot Jiří: Conformation Study of A-Ring in 19β,28-Epoxy-2-fluoro-18α-oleananes. Collect. Czech. Chem. Commun. 2006, 71, 368. <https://doi.org/10.1135/cccc20060368>
  • Müller Ralph, Rüedi Peter: An Unexpected (3→2)‐Hydride Shift in Phyllocladane (=13β‐Kaurane) Diterpenoids and in Related Trimethyl‐Substituted Bi‐ and Tricyclic Compounds. Helvetica Chimica Acta 2003, 86, 439. <https://doi.org/10.1002/hlca.200390044>
  • KLINOT J., SEJBAL J., VYSTRCIL A.: ChemInform Abstract: Triterpenes. Part 86. Triterpenoid 2,3‐Ketols, Diols and Their Acetates: Preparation and Conformation of the Ring A. ChemInform 1989, 20. <https://doi.org/10.1002/chin.198924267>