Collect. Czech. Chem. Commun.
1989, 54, 3083-3087
https://doi.org/10.1135/cccc19893083
Continuous wave CO2 laser driven oxidation of 2-butene and 2-octafluorobutene
Josef Pola and Josef Vítek
Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, 165 02 Prague 6-Suchdol
Abstract
CW CO2 laser induced reactions of 2-butene and 2-octafluorobutene with molecular ground state 3O2 oxygen in the presence of sulfur hexafluoride afford products that can be rationalized by means of the earlier proposed mechanism involving transient dioxetane and its cleavage into carbonyl compounds.
