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Collect. Czech. Chem. Commun. 1987, 52, 103-112
https://doi.org/10.1135/cccc19870103

Arachno-6,9-C2B8H14 dicarbaborane and its 1- and 5-monohalogenated derivatives

Bohumil Štíbr, Zbyněk Janoušek, Jaromír Plešek, Tomáš Jelínek and Stanislav Heřmánek

Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, 250 68 Řež

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  • Štíbr Bohumil: Alpha shift correlation (ASC) method. Sensitivity of 11B NMR shifts to halogen substitution in the ten-vertex nido and arachno series of boron clusters. Linear behavior of NMR effects. Inorganica Chimica Acta 2018, 471, 615. <https://doi.org/10.1016/j.ica.2017.11.040>
  • Štíbr Bohumil: Recent aspects of the ten-vertex dicarbaborane chemistry. Journal of Organometallic Chemistry 2018, 865, 4. <https://doi.org/10.1016/j.jorganchem.2018.01.010>
  • Bakardjiev Mario, Štíbr Bohumil, Holub Josef, Tok Oleg L., Švec Petr, Růžičková Zdeňka, Růžička Aleš: Sequential Camouflage of the arachno-6,9-C2B8H14 Cage by Substituents. Inorg. Chem. 2016, 55, 7068. <https://doi.org/10.1021/acs.inorgchem.6b00964>
  • Štíbr Bohumil: Ten-vertex dicarbaboranes from nido -5,6-C 2 B 8 H 12. Journal of Organometallic Chemistry 2015, 798, 30. <https://doi.org/10.1016/j.jorganchem.2015.04.005>
  • Štíbr Bohumil: Acyl chloride carbon insertion into dicarbaborane cages – new route to tricarbollide cages. Pure and Applied Chemistry 2015, 87, 135. <https://doi.org/10.1515/pac-2014-0937>
  • Štíbr Bohumil: Carbon insertion into borane clusters via nucleophilic addition reactions of borane and carborane anions. Journal of Organometallic Chemistry 2013, 747, 16. <https://doi.org/10.1016/j.jorganchem.2013.04.010>
  • Bakardjiev Mario, Štíbr Bohumil, Holub Josef, Padělková Zdeňka, Růžička Aleš: Carbon Insertion into arachno-6,9-C2B8H14 via Acyl Chlorides. Skeletal Alkylcarbonation (SAC) Reactions: A New Route for Tricarbollides. Inorg. Chem. 2013, 52, 9087. <https://doi.org/10.1021/ic401293g>
  • Štíbr Bohumil, Bakardjiev Mario, Holub Josef, Růžička Aleš, Padělková Zdeňka, Olejník Roman, Švec Petr: Skeletal Alkylcarbonation (SAC) Reactions as a Simple Design for Cluster–Carbon Insertion and Cross‐Coupling: High‐Yield Access to Substituted Tricarbollides from 6,9‐Dicarba‐arachno‐decaborane(14). Chemistry A European J 2011, 17, 13156. <https://doi.org/10.1002/chem.201102016>
  • Kiani Farooq Ahmad, Hofmann Matthias: Structural relationships among two vertex sharing macropolyhedral boranes. Dalton Trans. 2007, 1207. <https://doi.org/10.1039/b700270j>
  • Holub Josef, Bakardjiev Mario, Štíbr Bohumil: The Synthesis of 10-Halo-Substituted Derivatives of nido-7,8,9-PC2B8H11 and [nido-7,8,9-PC2B8H10]- and New Linear Correlations Between NMR Parameters. Collect. Czech. Chem. Commun. 2005, 70, 1861. <https://doi.org/10.1135/cccc20051861>
  • Štı́br Bohumil, Teixidor Francesc, Viñas Clara, Fusek Jiřı́: A convenient route to carbon-substituted derivatives of nido-5,6-C2B8H121Dedicated to Professor K. Wade on the occasion of his 65th birthday for his essential contributions to the area of cluster boron chemistry. All cluster chemists know Wade's electron-counting rules and use them for the benefit of chemistry.1. Journal of Organometallic Chemistry 1998, 550, 125. <https://doi.org/10.1016/S0022-328X(97)00535-4>
  • Štíbr Bohumil, Holub Josef, Císařová Ivana, Teixidor Francesc, Viñas Clara, Fusek Jiří, Plzák Zbyněk: The Derivatives of the 7,8,9- Series of Tricarbollides. Preparation and Structural Characterization of the 11-Vertex Tricarbaboranes 7-L-nido-7,8,9-C3B8H10 (L = Amines). Inorg. Chem. 1996, 35, 3635. <https://doi.org/10.1021/ic951437o>
  • Holub Josef, Štíbr Bohumil, Janoušek Zbyněk, Kennedy John D., Thornton-Pett Mark: Ten-vertex polyhedral dicarbaborane chemistry: new positional isomers of cluster constituents in the ten-vertex arachnodicarbaborane family: the patent [arachno-5,10-C2B8H13]− anion and the isomeric ligand derivatives exo-9-L-arachno-5,6-C2B8H12 and exo-6-L-arachno-5 ,10-C2B8H12. Inorg Chim Ada 1994, 221, 5. <https://doi.org/10.1016/0020-1693(94)03972-0>
  • Jelínek Tomás, Kennedy John D., Štíbr Bohumil: The first cluster azathiaboranes: isolation and characterisation of eight-vertex hypho-7,8-NSB6H11 and ten-vertex arachno-6,9-NSB8H11. J. Chem. Soc., Chem. Commun. 1993, 0, 1628. <https://doi.org/10.1039/C39930001628>
  • Davidson George: Chapter 3. Coord Chem Rev - 1990, 102, 146. <https://doi.org/10.1016/0010-8545(90)80004-D>
  • Fontaine Xavier L. R., Kennedy John D., Thornton-Pett Mark, Nestor Karl, Štíbr Bohumil, Jelínik Tomáš, Baše Karel: Polyhedral iridamonocarbaborane chemistry. Two ten-vertex arachno-6,9-iridacarbadecaboranes and some related ten-vertex carbaborane chemistry. Comparative nuclear magnetic resonance studies and the molecular structure of [asym-9-(CO)-9,9-(PPh3)2-9-H-arachno-9,6-IrCB8H12]. J. Chem. Soc., Dalton Trans. 1990, 2887. <https://doi.org/10.1039/DT9900002887>