Collect. Czech. Chem. Commun. 1987, 52, 93-102

Preparation and properties of green rust type substances

Jaroslav Vinš, Jan Šubrt, Vladimír Zapletal and František Hanousek

Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, 250 68 Řež


A method has been worked out for the reproducible preparation of Green Rust substances involving SO42-, Cl-, Br-, and I- anions. The chemical composition of the substances prepared has been followed in dependence on the synthesis conditions. The powder X-ray and electron diffraction patterns and infrared and Moessbauer spectra have been measured and discussed.