Collect. Czech. Chem. Commun.
1986, 51, 1450-1454
https://doi.org/10.1135/cccc19861450
5-Tricyanovinyl-2-furylation of aromatic derivatives
Dušan Berkeš and Jaroslav Kováč
Department of Organic Chemistry, Faculty of Chemical Technology, Slovak Institute of Technology, 812 37 Bratislava
Abstract
A new method for heteroarylation of aromatic derivatives has been developed. The highly reactive 2-bromo-5-tricyanovinylfuran acts in the presence of AlCl3 under conditions of Friedel-Crafts reaction as an electrophilic furylation reagent to give 5-aryl-2-tricyanovinylfurans with selected benzene and naphthalene derivatives.
