Collect. Czech. Chem. Commun.
1985, 50, 577-580
https://doi.org/10.1135/cccc19850577
Topological aspects of chemical reactivity. Theoretical justification of overlap determinant method
Robert Ponec
Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, 165 02 Prague 6-Suchdol
Abstract
The mutual relation of overlap determinant method and the selection rules in chemical reactivity has been analysed in terms of the technique of the configuration analysis. Such approach allows to prove the generality and the universality of the originally introduced criterion not only for thermal but also for photochemical reactions.
