Collect. Czech. Chem. Commun. 1984, 49, 1677-1679

Hydroformylation of propene catalyzed with carbonylchlorobis(triphenylphosphine)rhodium(I)

Milan Polievkaa, Alexandr Jegorovb, Ladislav Uhlára and Vendelín Machoa

a Research Institute of Petrochemistry, 972 71 Novaky
b Department of Inorganic Chemistry, Charles University, 128 40 Prague 2


Influence of some amines, amino acids, nitrogen heterocyclic compounds and urea derivatives (as ligands of carbonylchlorbis(triphenylphosphine)rhodium(I) on velocity of the catalyzed hydroformylation of propene has been investigated. A positive effect on the catalytic activity has been found with the modifying ligands of very low basicity.