Collect. Czech. Chem. Commun.
1984, 49, 2857-2866
https://doi.org/10.1135/cccc19842857
Contribution to the study of the kinetics of redox reactions proceeding via electrode processes. Theory of the method
Antonín Tockstein and Jaroslav Macenauer
Department of Physical Chemistry, Institute of Chemical Technology, 532 10 Pardubice
Abstract
A system of differential kinetic equations is derived for the redox reaction n2 Ox1 + n1 Red2 ⇌ n1 Ox2 + n2 Red1, proceeding only through electrode processes. Its numerical solution is compared with a simplified analytical solution which leads to linearization of the relations between measurable quantities and thus verification of the kinetic model used on real redox reactions.
