Collect. Czech. Chem. Commun.
1984, 49, 2437-2445
https://doi.org/10.1135/cccc19842437
The possibility of using chronopotentiometry in studies of ionic association or complexation at the interface between two immiscible electrolyte solutions
Emanuel Makrlík
Institute of Nuclear Research, 250 68 Řež
Abstract
Theoretical potential-time curves were derived in the form Δαβφ = f(t) (Δαβφ denotes Galvani potential difference between phases β and α), expressing mathematically a reversible transfer of a cation across the interface between two immiscible electrolyte solutions under galvanostatic conditions. The formation of ion pairs or complexes was taken into account, and the influence of certain components of two-phase systems on the form of potential-time curves is discussed.
