Collect. Czech. Chem. Commun.
1984, 49, 295-300
https://doi.org/10.1135/cccc19840295
Synthesis of 2-(S-aryloxycarbonylthio)ethyl isothiocyanates - Analogues of natural mustard oils
Pavol Kristian and Jozef Gonda
Department of Organic Chemistry and Biochemistry, P. J. Šafárik University, 041 67 Košice
Abstract
A simple reaction of 2-aryloxythiazolines with thiophosgene leads to formation of 2-(S-aryloxycarbonylthio)ethyl isothiocyanates. The starting thiazolines can easily be obtained from 2-bromoethyl isothiocyanates and phenolates. The structure of the products synthesized was evidenced by spectral methods.
