Collect. Czech. Chem. Commun. 1983, 48, 2147-2155

To the question whether higher associates exist in the vapour phase of acetic acid

Ivona Malijevsk√°

Department of Physical Chemistry, Prague Institute of Chemical Technology, 166 28 Prague 6


Equilibrium constants for higher associates in an ideal-gas associating mixture are correlated from existing data on the P-V-T behaviour of acetic acid. Further, a model of real-gas dimerizing mixture is tested on the basis of estimated critical properties for monomer and dimer of fatty acids.