Collect. Czech. Chem. Commun. 1983, 48, 1564-1570
https://doi.org/10.1135/cccc19831564

On separation of inductive and resonance effect

Robert Ponec

Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, 165 02 Prague 6-Suchdol

Abstract

On the basis of minimization of the properly defined objective function, a general method for separation of inductive and resonance effect has been proposed. Comparison of the so calculated results with characteristics obtained independently by perturbation theory of substituent effect made it possible to discuss mechanism of the transmission of inductive effect in aromatic and aliphatic series.