Collect. Czech. Chem. Commun. 1983, 48, 3329-3339

Studies on copper(I) complexes of some monoaryl thioureas

Anjali Bajpai, Deen D. Mishra and Udai D. N. Bajpai

Department of Post-Graduate Studies and Research in Chemistry, University of Jabalpur, Jabalpur-482 001, India


The copper(I) complexes of o-tolyl-, phenyl-, o-anisyl- and o-chlorophenyl thiourea have been prepared. The IR, NMR and thermal analysis of these complexes has shown that the coordination occurs through the nitrogen atom of the NH2 group except in the case of o-tolyl thiourea complex where it is through the substituted nitrogen atom. The complexes are either monomeric or dimeric in nature.