Collect. Czech. Chem. Commun. 1982, 47, 2097-2109
https://doi.org/10.1135/cccc19822097

Kinetics of ammonia oxidation on cobalt catalyst II application of tubular reactor with catalytically active wall

Bohumil Bernauer, Antonín Šimeček and Jan Vosolsobě

Department of Inorganic Technology, Prague Institute of Chemical Technology, 166 28 Prague 6

Abstract

The kinetics of ammonia oxidation on cobalt catalyst is described on basis of experimental data measured in the tubular reactor with catalytically active wall. In the temperature range up to 623 K, where the products of ammonia oxidation are nitrogen monoxide and elementary nitrogen, it is possible to describe the rate of formation of these components by empirical equations (5) and (6), at the temperature above 900 K, where the products are nitrogen dioxide and elementary nitrogen, by equations (7) and (8).