Collect. Czech. Chem. Commun. 1981, 46, 2663-2668

Hyperconjugation in organosilicon chemistry

Robert Ponec, Luboš Dejmek and Václav Chvalovský

Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, 165 02 Prague 6-Suchdol


The extent of delocalization interactions in organosilicon compounds was investigated by using the projection method of maximum localization. The results confirm that the accuracy of the localized model for organosilicon compounds is lower than that for analogous carbofunctional compounds.