Collect. Czech. Chem. Commun. 1980, 45, 1336-1342

Structure of dimeric monoisopropoxydicaprolactamoalane and diisopropoxymonocaprolactamoalane

Otomar Kříž, Bohuslav Čásenský and Jiří Macháček

Institute of Inorganic Chemistry, Czechoslovak Academy of Sciences, 250 68 Řež


Molecular weight and 1H-NMR and IR spectral measurements evidence that in dimeric aluminium isopropoxide in which one or two isopropoxyls have been replaced by caprolactam ligand, only the oxygen atoms of the isopropoxyl take part in the bridge formation between the two aluminium atoms.