Collect. Czech. Chem. Commun. 1979, 44, 2096-2100
https://doi.org/10.1135/cccc19792096

5-Nitro-2-furylvinylation of aromatic compounds

Ján Hrabovský and Jaroslav Kováč

Department of Organic Chemistry, Slovak Institute of Technology, 880 37 Bratislava

Abstract

A new synthesis of (E)-2-(4-X-phenyl)-1-(5-nitro-2-furyl)ethylenes (X = H, CH3, OH, OCH3), 2-(2-naphthyl)-1-(5-nitro-2-furyl)ethylene and 2-(2-thienyl)-1-(5-nitro-2-furyl)ethylene from (Z)-2-bromo-1-(5-nitro-2-furyl)ethylene and the respective aromatic or heteroaromatic derivative under catalysis of aluminium chloride is described.