Collect. Czech. Chem. Commun.
1979, 44, 234-245
https://doi.org/10.1135/cccc19790234
Westphalen rearrangement. Mechanism of formation of 5α-acetoxy derivatives
Pavel Kočovskýa, Václav Černýa and František Turečekb
a Institute of Organic Chemistry and Biochemistry, Czechoslovak Academy of Sciences, 166 10 Prague 6
b The J. Heyrovský Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, 121 38 Prague 2
Crossref Cited-by Linking
- Ramírez Hernández Johana, Sandoval-Ramírez Jesús, Meza-Reyes Socorro, Vega Báez José Luis, Bernès Sylvain: Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate. Acta Crystallogr E Struct Rep Online 2012, 68, o3331. <https://doi.org/10.1107/S1600536812045278>
- Pinto Rui M.A., Salvador Jorge A.R., Le Roux Christophe, Carvalho Rui A., Silva Manuela Ramos, Beja Ana Matos, Paixão José A.: Bismuth(III) salt-catalyzed Westphalen and “backbone” rearrangements of 5β,6β-epoxysteroids. Steroids 2008, 73, 549. <https://doi.org/10.1016/j.steroids.2008.01.006>
- Kohno Harumichi, Iwakuma a) Takeo, Yamada Koichiro: A Simple and Efficient Procedure for the Synthesis of Optically Active 4-Methoxy-α-Methylphenylethylamine from Tyrosine. Synthetic Communications 1998, 28, 1935. <https://doi.org/10.1080/00397919808007167>
- Kamernitskii A. V., Reshetova I. G., Chernov S. V.: Skeletal rearrangements in steroids and polycyclic triterpenoids (review). Pharm Chem J 1987, 21, 736. <https://doi.org/10.1007/BF00758138>
- Kočovsk Pavel, Starý Ivo, Tureček František: On the deceptive behavior of tri-n-butyltin hydride: In the reduction of acetates of some bromohydrins. A stereospecific radical rearrangement. Tetrahedron Letters 1986, 27, 1513. <https://doi.org/10.1016/S0040-4039(00)84300-2>
- Nashed Nashaat T., Michaud Dennis P., Levin Wayne, Jerina Donald M.: Properties of liver microsomal cholesterol 5,6-oxide hydrolase. Archives of Biochemistry and Biophysics 1985, 241, 149. <https://doi.org/10.1016/0003-9861(85)90371-6>
- Francis Schuda Paul, Heimann Martha R.: The synthesis of dl-coriolin. Tetrahedron 1984, 40, 2365. <https://doi.org/10.1016/0040-4020(84)80020-4>
- KOCOVSKY P., CERNY V., TURECEK F.: ChemInform Abstract: STEROIDS. CCXIII. WESTPHALEN REARRANGEMENT. MECHANISM OF FORMATION OF 5α‐ACETOXY DERIVATIVES. Chemischer Informationsdienst 1979, 10. <https://doi.org/10.1002/chin.197917346>