Collect. Czech. Chem. Commun. 1976, 41, 119-130
https://doi.org/10.1135/cccc19760119

Methylation and ethylation of the aryl-activated benzylic group and formation of gem-diarylcyclopropanes by means of bis(2-alkoxyethoxy)aluminium hydrides

M. Černý and J. Málek

Individual author index pages


Other CCCC articles of these authors

  • M. Černý
    Synthesis of an optically active silylated diphosphine and related dinitrile derived from L-(+)-tartaric acid
    1977, Vol. 42, Issue 10, pp. 3069–3078 [Abstract]
  • P. Čársky and J. Málek
    CNDO/S and INDO/S calculations on small aluminium compounds
    1977, Vol. 42, Issue 9, pp. 2758–2766 [Abstract]
  • M. Hájek and J. Málek
    Radical addition of nitriles to 1-alkenes initiated by metal oxides
    1977, Vol. 42, Issue 8, pp. 2388–2393 [Abstract]
  • P. Šilhavý, J. Vejrosta and J. Málek
    Kinetics of formation of β-hydroxyethylpyridinium benzoate in the reaction of pyridine with ethylene oxide and benzoic acid in protic medium
    1977, Vol. 42, Issue 2, pp. 495–507 [Abstract]
  • J. Pacák, M. Braunová, D. Štropová and M. Černý
    Fluorinated derivatives of 1,6-anhydro-β-D-ribo-hexopyranos-3-ulose
    1977, Vol. 42, Issue 1, pp. 120–131 [Abstract]
  • O. M. O. Habib and J. Málek
    Linear free energy relationships in a metal ion-catalysed esterification of substituted benzoic acids with ethylene glycol
    1976, Vol. 41, Issue 10, pp. 3077–3084 [Abstract]
  • R. Ponec and J. Málek
    SCF-LCI theory of substituent effect
    1976, Vol. 41, Issue 10, pp. 3027–3034 [Abstract]
  • M. Černý, I. Černý and J. Pacák
    Preparation of 4-amino-1,6-anhydro-4-deoxy-β-D-glucopyranose. Isomerization of 4-amino-1,6 : 2,3-dianhydro-4-deoxy-β-D-mannopyranose to 1,6-anhydro-3,4-dideoxy-3,4-epimino-β-D-altropyranose
    1976, Vol. 41, Issue 10, pp. 2942–2951 [Abstract]
  • O. M. O. Habib and J. Málek
    The activity of metal ions in catalytic esterification of aromatic carboxylic acids with aliphatic glycols
    1976, Vol. 41, Issue 9, pp. 2724–2736 [Abstract]
  • O. M. O. Habib and J. Málek
    The effect of the structure of aromatic amides and aliphatic glycols on the rate of a metal ion-catalysed glycolytic reaction
    1976, Vol. 41, Issue 9, pp. 2543–2555 [Abstract]
  • J. Doležalová, M. Černý, T. Trnka and J. Pacák
    Preparation of 1,6-anhydro derivatives of 2,4-dideoxy-2-fluoro-β-D-xylo-hexopyranose and 2,3-dideoxy-2-fluoro-β-D-ribo-hexopyranose and corresponding reducing sugars
    1976, Vol. 41, Issue 7, pp. 1944–1953 [Abstract]
  • M. Hájek and J. Málek
    Silver(I) oxide and silver(II) oxide initiated alkylation of cycloalkanones with alkenes
    1976, Vol. 41, Issue 3, pp. 746–757 [Abstract]
  • J. Málek and E. Zelená
    Kinetics of the glycolysis of aromatic carboxamides catalysed in solution by metal ions
    1976, Vol. 41, Issue 2, pp. 395–407 [Abstract]
  • J. Schraml, J. Pola, H. Jancke, G. Engelhardt, M. Černý and V. Chvalovský
    Application of 29Si-NMR to analysis of silylated compounds. NMR spectra of (CH3)3Si-O-C derivatives
    1976, Vol. 41, Issue 2, pp. 360–367 [Abstract]
  • M. Černý
    Preparation and properties of some o-, m-, and p-phenoxyarylsiloxanes
    1976, Vol. 41, Issue 1, pp. 114–118 [Abstract]
  • M. Černý
    Preparation of diphenylalkoxychlorosilanes and diphenyldialkoxysilanes
    1976, Vol. 41, Issue 1, pp. 110–113 [Abstract]
  • J. Málek and P. Šilhavý
    The catalytic activity of tertiary phosphines, arsines, stibines, and quarternary phosphonium salts in reaction of terephthalic acid with ethylene oxide
    1976, Vol. 41, Issue 1, pp. 101–109 [Abstract]
  • J. Málek and P. Šilhavý
    Kinetics and mechanism of the reaction of aromatic carboxylic acids with ethylene oxide in protic and aprotic dipolar solvents in the presence of tertiary amines
    1976, Vol. 41, Issue 1, pp. 84–100 [Abstract]
  • T. Trnka, M. Černý, M. Buděšínský and J. Pacák
    The synthesis of 3-amino-3-deoxy-D-glucose (kanosamine) and its 1,6-anhydro derivative conformation of amino derivatives of 1,6-anhydro-β-D-hexopyranoses
    1975, Vol. 40, Issue 10, pp. 3038–3045 [Abstract]
  • Azza Amin Ahmed El-Attar and M. Černý
    The preparation and thermal behaviour of some polyarylsilanes
    1975, Vol. 40, Issue 9, pp. 2806–2815 [Abstract]
  • M. Černý
    The preparation and properties of some phenoxyarylsilanes
    1975, Vol. 40, Issue 9, pp. 2642–2648 [Abstract]
  • M. Černý, O. Juláková, J. Pacák and M. Buděšínský
    Isomerization of 2-amino-1,6 : 3,4-dianhydro-2-deoxy-β-D-galactopyranose to 1,6-anhydro-2,3-dideoxy-2,3-epimino-β-D-gulopyranose in alkaline medium
    1975, Vol. 40, Issue 7, pp. 2116–2119 [Abstract]
  • J. Frgala, M. Černý and J. Staněk, jr
    Preparation of alkyl 1-thio-β-D-galactopyranosides substituted in the alkyl with reactive groups
    1975, Vol. 40, Issue 5, pp. 1411–1425 [Abstract]
  • J. Pacák, J. Hriňák and M. Černý
    The synthesis of 6-amino-2,6-dideoxy-2-fluoro-D-glucose
    1974, Vol. 39, Issue 11, pp. 3332–3337 [Abstract]
  • M. Hájek, P. Šilhavý and J. Málek
    Hydrolysis of aromatic nitriles by alkaline hydrogen peroxide
    1974, Vol. 39, Issue 9, pp. 2667–2672 [Abstract]
  • J. Málek, M. Černý and R. Řeřicha
    Formation of anionic intermediates in the reduction and alkylation of anthracene and its derivatives by sodium bis(2-methoxyethoxy)aluminum hydride
    1974, Vol. 39, Issue 9, pp. 2656–2666 [Abstract]
  • M. Černý, M. Kollmann, J. Pacák and M. Buděšínský
    Preparation of branched-chain hexoses by reaction of 1,6-anhydro-2,4-di-O-p-toluenesulfonyl-β-D-hexopyranos-3-uloses with Grignard reagents
    1974, Vol. 39, Issue 9, pp. 2507–2519 [Abstract]
  • V. Bažant and M. Černý
    Synthesis of p-chlorophenyldiphenylsilanes and unsymmetrical p-bis-silylarylenes from p-dichlorobenzene and p-bromochlorobenzene by the Grignard reaction
    1974, Vol. 39, Issue 7, pp. 1880–1884 [Abstract]
  • M. Černý, T. Elbert and J. Pacák
    Preparation of 1,6-anhydro-2,3-dideoxy-2,3-epimino-β-D-mannopyranose and its conversion to 2-amino-1,6-anhydro-2-deoxy-β-D-mannopyranose
    1974, Vol. 39, Issue 7, pp. 1752–1767 [Abstract]
  • V. Bažant and M. Černý
    Synthesis of p-bis-silylarylene compounds by the Grignard reaction of p-dibromobenzene with dialkoxy-, dichloro-, alkoxychloro- and chlorodiphenylsilanes
    1974, Vol. 39, Issue 7, pp. 1735–1739 [Abstract]
  • V. Bažant and M. Černý
    Synthesis of p-bis-silylarylene compounds by the Grignard reaction of p-dichlorobenzene with dialkoxy-, dichloro-, alkoxychloro- and chlorodiphenylsilanes
    1974, Vol. 39, Issue 7, pp. 1728–1734 [Abstract]
  • M. Černý, O. Juláková and J. Pacák
    Preparation of 2-amino-1,6-anhydro-2-deoxy-β-D-glucopyranose and 2-amino-1,6:3,4-dianhydro-2-deoxy-β-D-galactopyranose
    1974, Vol. 39, Issue 5, pp. 1391–1396 [Abstract]
  • J. Pecka, J. Staněk, jr and M. Černý
    Preparation and the properties of 2,3-, 2,4-, and 3,4-dideoxy derivatives of 1,6-anhydro-β-D-glycero-hexopyranosuloses and corresponding alcohols
    1974, Vol. 39, Issue 5, pp. 1192–1209 [Abstract]
  • M. Krumpolc, V. Bažant and J. Málek
    Formation of linear oligomers in the initial phase of polyesterification of terephthalic acid
    1974, Vol. 39, Issue 5, pp. 1158–1168 [Abstract]
  • M. Černý and J. Málek
    Simultaneous hydrogenolysis and alkylation of aromatic ketones by sodium bis(2-methoxyethoxy)aluminum hydride at elevated temperatures
    1974, Vol. 39, Issue 3, pp. 842–853 [Abstract]
  • J. Pacák, P. Drašar, D. Štropová, M. Černý and M. Buděšínský
    Syntheses with anhydro sugars. XVIII. Aminodideoxyfluorine derivatives of D-glucose
    1973, Vol. 38, Issue 12, pp. 3936–3939 [Abstract]
  • J. Nývlt, H. Kočová and M. Černý
    Size distribution of crystals from a batch crystallizer
    1973, Vol. 38, Issue 11, pp. 3199–3209 [Abstract]
  • J. Halbych, T. Trnka and M. Černý
    Syntheses with anhydro sugars. XVII. Preparation and reactions of 1,6:2,3-dianhydro-4-deoxy- and 1,6:3,4-dianhydro-2-deoxy-β-D-hexopyranoses with nucleophilic and reducing reagents
    1973, Vol. 38, Issue 7, pp. 2151–2166 [Abstract]
  • J. Pacák, P. Drašar, J. Nerudová and M. Černý
    Syntheses with anhydro sugars. XIV. Synthesis of some derivatives of 1,6-anhydro-4-deoxy-4-fluoro-β-D-glucopyranose
    1972, Vol. 37, Issue 12, pp. 4120–4125 [Abstract]
  • J. Pacák, J. Halásková, V. Štěpán and M. Černý
    Synthesis of 1,6-dideoxy-1,6-difluoro-D-fructose
    1972, Vol. 37, Issue 11, pp. 3646–3651 [Abstract]
  • T. Trnka and M. Černý
    Syntheses with anhydro sugars. XIII. Preparation of the deoxy derivatives of the 1,6-anhydro-β-D-hexopyranoses by catalytic reduction of 1,6:2,3- and 1,6:3,4-dianhydro-β-D-hexopyranoses
    1972, Vol. 37, Issue 11, pp. 3632–3639 [Abstract]
  • M. Černý, V. Přikrylová and J. Pacák
    Syntheses with anhydro sugars. XII. Preparation of 2,6-dideoxy-2-fluoro-D-glucose
    1972, Vol. 37, Issue 9, pp. 2978–2984 [Abstract]
  • J. Pacák, J. Podešva, Z. Točík and M. Černý
    Syntheses with anhydro sugars. XI. Preparation of 2-deoxy-2-fluoro-D-glucose and 2,4-dideoxy-2,4-difluoro-D-glucose
    1972, Vol. 37, Issue 8, pp. 2589–2599 [Abstract]
  • M. Černý and J. Málek
    Properties of sodium bis(2-methoxyethoxy)aluminium hydride. XII. Reduction and hydrogenolysis of sodium and bromomagnesium salts of some aliphatic and aromatic carboxylic acids
    1971, Vol. 36, Issue 6, pp. 2394–2397 [Abstract]
  • T. Trnka and M. Černý
    Syntheses with anhydro sugars. X. Cleavage of oxiran ring in 1,6:2,3- and 1,6:3,4-dianhydro-β-D-hexopyranoses with potassium hydroxide and sulfuric acid
    1971, Vol. 36, Issue 6, pp. 2216–2225 [Abstract]
  • M. Hájek, J. Málek and V. Bažant
    Kinetics of thermal decomposition of ammonium salts of terephthalic and isophthalic acids
    1971, Vol. 36, Issue 1, pp. 84–91 [Abstract]
  • M. Černý and J. Málek
    Properties of sodium bis(2-methoxyethoxy)aluminium hydride. XI. Reduction and hydrogenolysis of hydroxy-substituted aldehydes, ketones, carboxylic acids and carbinols of the naphthalene series
    1970, Vol. 35, Issue 10, pp. 3079–3084 [Abstract]
  • M. Černý and J. Málek
    Über die Eigenschaften von Natrium-bis-(2-methoxyäthoxy)aluminiumhydrid X. Reduktion und Hydrogenolyse einiger hydroxy- und alkoxysubstituierten aromatischen Carbinole, Aldehyde, Ketone, Carbonsäuren und ihrer Derivate
    1970, Vol. 35, Issue 7, pp. 2030–2043 [Abstract]
  • M. Černý and J. Málek
    Properties of sodium bis(2-methoxyethoxy)aluminium hydride. IX. Reduction and hydrogenolysis of amino-substituted aromatic aldehydes, ketones, carboxylic acids, esters, and carbinols
    1970, Vol. 35, Issue 4, pp. 1216–1223 [Abstract]
  • J. Hradil and J. Málek
    Veresterung von Benzolcarbonsäuren mit Äthylenglykol II. Kinetik der Veresterung von Benzoesäure in Gegenwart von Zinkkatalysatoren
    1969, Vol. 34, Issue 12, pp. 3959–3966 [Abstract]
  • M. Černý, T. Trnka, P. Beran and J. Pacák
    Syntheses with anhydro sugars. VIII. Preparation of 1,6:2,3-dianhydro- and 1,6:3,4-dianhydro-β-D-allopyranose
    1969, Vol. 34, Issue 11, pp. 3377–3382 [Abstract]
  • M. Černý, J. Staněk, Jr. and J. Pacák
    Syntheses with anhydrosugars. VII. Preparation of 4-deoxy-D-ribo-hexose (4-deoxy-D-allose), 4-deoxy-D-lyxo-hexose (4-deoxy-D-mannose) and of their 1,6-anhydro derivatives
    1969, Vol. 34, Issue 6, pp. 1750–1765 [Abstract]
  • M. Černý, J. Málek, M. Čapka and V. Chvalovský
    Properties of sodium bis-(2-methoxyethoxy)aluminium hydride. IV. Reduction of oximes, amides, lactams, imides and nitriles
    1969, Vol. 34, Issue 3, pp. 1033–1041 [Abstract]
  • M. Černý, J. Málek, M. Čapka and V. Chvalovský
    Properties of sodium bis-(2-methoxyethoxy)aluminium hydride. III. Reduction of carboxylic acids and their derivatives
    1969, Vol. 34, Issue 3, pp. 1025–1032 [Abstract]
  • M. Černý, J. Staněk, Jr. and J. Pacák
    Syntheses with anhydro sugars. VI. The reactivity of p-toluenesulfonyl esters of 1,6-anhydro-β-D-glucopyranose during the formation of epoxy derivatives in alkaline medium
    1969, Vol. 34, Issue 3, pp. 849–856 [Abstract]
  • P. Čefelín and J. Málek
    On the kinetics of polycondensation of bis(2-hydroxyethyl) terephthalate
    1969, Vol. 34, Issue 2, pp. 419–426 [Abstract]
  • M. Černý, L. Kalvoda and J. Pacák
    Syntheses with anhydro sugars. V. Preparation of 2,4-di-O-substituted 1,6-anhydro-β-D-hexopyranos-3-uloses and their isomerization and reduction
    1968, Vol. 33, Issue 4, pp. 1143–1156 [Abstract]
  • J. Staněk, M. Šindlerová, O. Hánová, M. Černý and J. Pacák
    Synthese nichtreduzierender Thiodisaccharide
    1965, Vol. 30, Issue 7, pp. 2494–2497 [Abstract]
  • M. Černý, J. Pacák and J. Staněk
    Synthesen mit Anhydrozuckern IV. Darstellung von 1,6-2,3-Dianhydro-β-D-mannopyranose und ihre Isomerisierung zu 1,6-3,4-Dianhydro-β-D-altropyranose
    1965, Vol. 30, Issue 4, pp. 1151–1157 [Abstract]
  • J. Staněk, M. Šindlerová and M. Černý
    Derivatives of D-thioxylopyranose and of some reducing 1-deoxy-1-thiodisaccharides
    1965, Vol. 30, Issue 1, pp. 297–303 [Abstract]
  • J. Málek and R. Lukeš
    Darstellung von 1-Isopropenyl-1-cyclopenten
    1963, Vol. 28, Issue 9, pp. 2520–2523 [Abstract]
  • M. Černý, I. Buben and J. Pacák
    Synthesen mit Anhydrozuckern III. Über die Reaktion von 2-O-Tosyl-1,6:3,4-dianhydro-β-D-galaktopyranose mit Natriumhydroxyd
    1963, Vol. 28, Issue 6, pp. 1569–1578 [Abstract]
  • J. Pacák and M. Černý
    Darstellung und Strukturnachweis von 4,6-O-Benzyliden-D-galaktopyranose
    1963, Vol. 28, Issue 2, pp. 541–544 [Abstract]
  • M. Černý and J. Pacák
    Desoxyzucker III. Über Reaktionen der 2-O-Tosyl-1,6:3,4-dianhydro-β-D-galaktopyranose Darstellung von 4-Desoxy-D-xylohexose (4-Desoxy-D-glucose) und 4-Desoxy-D-arabinohexose (4-Desoxy-D-altrose)
    1962, Vol. 27, Issue 1, pp. 94–105 [Abstract]
  • R. Lukeš and M. Černý
    Reaktion des Allylmagnesiumbromids mit O-Methylvalerolactim
    1961, Vol. 26, Issue 11, pp. 2886–2890 [Abstract]
  • M. Černý, V. Gut and J. Pacák
    Partielle Substitution der 1,6-Anhydro-β-D-glucopyranose
    1961, Vol. 26, Issue 10, pp. 2542–2550 [Abstract]
  • J. Pacák and M. Černý
    1,2:3,4-Di-O-benzyliden-D-galaktopyranose
    1961, Vol. 26, Issue 9, pp. 2212–2216 [Abstract]
  • M. Černý, D. Zachystalová and J. Pacák
    Darstellung acetylierter aromatischer β-D-Thioglucopyranoside durch Reaktion von Diazoniumsalzen mit 2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosylmercaptan
    1961, Vol. 26, Issue 9, pp. 2206–2211 [Abstract]
  • M. Černý and J. Pacák
    Darstellung von 2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosylmercaptan und von Natrium- und Gold-β-D-glucopyranosylmercaptid
    1961, Vol. 26, Issue 8, pp. 2084–2086 [Abstract]
  • J. Pacák and M. Černý
    Kondensation von Sacchariden mit Carbonylverbindungen in Gegenwart von Metaphosphorsäureäthylester
    1959, Vol. 24, Issue 11, pp. 3804–3807 [Abstract]
  • R. Lukeš and M. Černý
    Einwirkung des Grignard-Reagenz auf die Amidgruppe XXV. Darstellung von 1-Methyl-2-allylpiperidin
    1959, Vol. 24, Issue 11, pp. 3596–3600 [Abstract]
  • L. Lacko, J. Málek and J. Dvořáková
    Über Dextran VIII. Einfluss von Kationen und Salzgemischen auf die Löslichkeit des Dextrans in wässrig-alkoholischer Lösung
    1959, Vol. 24, Issue 9, pp. 2954–2958 [Abstract]
  • R. Lukeš and M. Černý
    Über die Einwirkung des Grignard-Reagenz auf die Amidgruppe XXV. Über die Reaktion von Allylmagnesiumbromid mit Glutarsäuremethylimid
    1959, Vol. 24, Issue 8, pp. 2722–2726 [Abstract]
  • M. Černý and J. Pacák
    Eine neue Methode zur Darstellung acetylierter β-D-Thioglucopyranoside
    1959, Vol. 24, Issue 8, pp. 2566–2570 [Abstract]
  • R. Lukeš and M. Černý
    Ein neues Darstellungsverfahren für 1-Methyl-2-alkylpiperidine
    1959, Vol. 24, Issue 4, pp. 1287–1290 [Abstract]
  • J. Staněk and M. Černý
    Zur Bildung von Acetylderivaten der Glykosylamine
    1959, Vol. 24, Issue 3, pp. 1017–1019 [Abstract]
  • M. Černý, J. Vrkoč and J. Staněk
    Über die Darstellung von acylierten Derivaten der Glucopyranosylmercaptane
    1959, Vol. 24, Issue 1, pp. 64–69 [Abstract]
  • R. Lukeš and M. Černý
    Über die Einwirkung von Grignard-Reagenz auf die Amidgruppe XX. Die Reaktion von Vinylmagnesiumbromid mit Glutarsäuremethylimid
    1958, Vol. 23, Issue 5, pp. 946–953 [Abstract]
  • L. Lacko and J. Málek
    Über Dextran VI. Der Einfluss der Dextrankonzentration, der Temperatur und des pH auf die Löslichkeit des Dextrans in wässrigalkoholischen Lösungen verschiedener Ionenstärke
    1958, Vol. 23, Issue 5, pp. 828–832 [Abstract]
  • R. Lukeš and M. Černý
    Über die Einwirkung des Grignard-Reagenz auf die Amidgruppe XIX. Darstellung von einigen höheren 4-Ketosäuren
    1958, Vol. 23, Issue 3, pp. 497–503 [Abstract]
  • J. Pacák and M. Černý
    Anwendung von Metaphosphorsäure-äthylester zur Darstellung von Isopropylidenderivaten unsubstituierter Monosaccharide
    1958, Vol. 23, Issue 3, pp. 490–496 [Abstract]
  • L. Lacko and J. Málek
    Über Dextran IV. Die Wirkung von Phosphaten auf die Löslichkeit der Dextrane von verschiedenem Molekulargewicht in wässrig alkoholischer Lösung
    1958, Vol. 23, Issue 3, pp. 361–366 [Abstract]
  • L. Lacko and J. Málek
    Über Dextran III. Der Einfluss von Salzen auf die Löslichkeit teilweise abgebauten Dextrans in wässrig-alkoholischer Lösung
    1957, Vol. 22, Issue 4, pp. 1110–1113 [Abstract]
  • L. Lacko and J. Málek
    Über Dextran II. Die Bestimmung des Zahlendurchschnittes des Moleculargewichtes von teilweise abgebautem Dextran mittels der jodometrischen Methode
    1957, Vol. 22, Issue 4, pp. 1106–1109 [Abstract]
  • M. Černý and J. Pacák
    Desoxysugars. II. Preparation of 3-desoxy-D-glucose and some of its derivatives
    1956, Vol. 21, Issue 4, pp. 1003–1006 [Abstract]
  • A. Kleinzeller and J. Málek
    Biosynthesis of fats from saccharides by yeasts. IV. The metabolism of Rhodotorula gracilis on glucose, D-xylose and sodium acetate
    1953, Vol. 18, Issue 3, pp. 428–438 [Abstract]
  • V. Horák and M. Černý
    Eine neue Methode zur Darstellung von Penthianonen
    1953, Vol. 18, Issue 3, pp. 379–383 [Abstract]
  • R. Lukeš and J. Málek
    The action of Grignard reagents on the amide group. XVI. 1-Methyl-1-azacyclononan-2-one
    1951, Vol. 16, pp. 23–32 [Abstract]