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Collect. Czech. Chem. Commun. 1972, 37, 1425-1444
https://doi.org/10.1135/cccc19721425

Statistics of the enthalpy-entropy relationship. I. The special case

O. Exner

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  • Janković Bojan, Marinović-Cincović Milena, Janković Marija: A new data in the kinetic and thermodynamic analysis of non-isothermal decomposition of super-fine kaolin powder. Applied Clay Science 2018, 156, 160. <https://doi.org/10.1016/j.clay.2018.02.008>
  • Hussein Ahmed K., Elbeih Ahmed, Zeman Svatopluk: Thermo-analytical study of a melt cast composition based on cis-1,3,4,6-tetranitrooctahydroimidazo-[4,5 d]imidazole (BCHMX)/trinitrotoluene (TNT) compared with traditional compositions. Thermochimica Acta 2018, 666, 91. <https://doi.org/10.1016/j.tca.2018.06.006>
  • Cornish-Bowden Athel: Enthalpy–entropy compensation and the isokinetic temperature in enzyme catalysis. J Biosci 2017, 42, 665. <https://doi.org/10.1007/s12038-017-9719-0>
  • Bushuev Mark B., Pishchur Denis P., Korolkov Ilya V., Vinogradova Katerina A.: Prototypical iron(ii) complex with 4-amino-1,2,4-triazole reinvestigated: an unexpected impact of water on spin transition. Phys. Chem. Chem. Phys. 2017, 19, 4056. <https://doi.org/10.1039/C6CP06854E>
  • Bushuev Mark B., Pishchur Denis P., Nikolaenkova Elena B., Krivopalov Viktor P.: Compensation effects and relation between the activation energy of spin transition and the hysteresis loop width for an iron(ii) complex. Phys. Chem. Chem. Phys. 2016, 18, 16690. <https://doi.org/10.1039/C6CP01892K>
  • RAVI R., SANJEEV R., JAGANNADHAM V., SKELTON ADAM A.: Nucleophilic Substitution Reactions of Meta‐ and Para‐Substituted Benzylamines with Benzyl Bromide in Methanol Medium. Int J of Chemical Kinetics 2015, 47, 36. <https://doi.org/10.1002/kin.20890>
  • Jain Bhawana, Singh Ajaya Kumar, Negi Reena: Mechanistic study of [RuCl3(H2O)2OH]− catalyzed oxidation of l-leucine by acidic N-bromophthalimide. J IRAN CHEM SOC 2015, 12, 1717. <https://doi.org/10.1007/s13738-015-0646-4>
  • Joseph Abhinav, Bernardes Carlos E. S., Viana Ana S., Piedade M. Fátima M., Minas da Piedade Manuel E.: Kinetics and Mechanism of the Thermal Dehydration of a Robust and Yet Metastable Hemihydrate of 4-Hydroxynicotinic Acid. Crystal Growth & Design 2015, 15, 3511. <https://doi.org/10.1021/acs.cgd.5b00594>
  • Ravi R., Sanjeev R., Jagannadham V.: Nonlinear Taft Polar Free Energy Relationship: Reactions of N‐Substituted Benzyl Amines with Benzyl Bromide in Methanol. Int J of Chemical Kinetics 2013, 45, 803. <https://doi.org/10.1002/kin.20818>
  • Nesprias Rosa, Eyler Gladys, Cañizo Adriana: Mono, Di and Trifunctional Cyclic Organic Peroxides: The Effect of Substituents and Ring Size on their Thermolysis in 1,4-dioxan. Aust. J. Chem. 2013, 66, 1080. <https://doi.org/10.1071/CH13171>
  • Barrie Patrick J.: The mathematical origins of the kinetic compensation effect: 1. the effect of random experimental errors. Phys. Chem. Chem. Phys. 2012, 14, 318. <https://doi.org/10.1039/C1CP22666E>
  • Nesprias Karina, Iglesias Mariángeles, Rivas Sonia, Alvarez Elida, Barreto Gastón, Eyler Nora, Cañizo Adriana: 4‐Heptanone cyclic diperoxide: Improved preparation method and solvent effect on its thermolysis in solution. Int J of Chemical Kinetics 2011, 43, 657. <https://doi.org/10.1002/kin.20600>
  • Olsson Tjelvar S. G., Ladbury John E., Pitt Will R., Williams Mark A.: Extent of enthalpy–entropy compensation in protein–ligand interactions. Protein Science 2011, 20, 1607. <https://doi.org/10.1002/pro.692>
  • Malode Shweta J., Shetti Nagaraj P., Nandibewoor Sharanappa T.: Os(VIII)/Ru(III) Catalysed Oxidation of l-Valine by Ag(III) Periodate Complex in Aqueous Alkaline Medium: A Comparative Kinetic Study. Catal Lett 2011, 141, 1526. <https://doi.org/10.1007/s10562-011-0623-1>
  • Katre Y. R., Joshi Ghanat K., Singh Ajaya K.: Effect of Anionic Surfactant on the Oxidation of DL-Aspartic Acid byN-Bromophthalimide: A Kinetic Study. Journal of Dispersion Science and Technology 2011, 32, 1434. <https://doi.org/10.1080/01932691.2010.513303>
  • Lamani Shekappa D., Veeresh Tegginamat M., Nandibewoor Sharanappa T.: Mechanism of Uncatalyzed and Osmium(VIII) Catalyzed Oxidation of L-alanine by Copper(III) Periodate Complex in Aqueous Alkaline Medium. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 2011, 41, 394. <https://doi.org/10.1080/15533174.2011.556408>
  • Hosamani Ragunatharaddi R., Hegde Rajesh N., Nandibewoor Sharanappa T.: Mechanistic study on the oxidation of l-phenylalanine by copper(III) in aqueous alkaline medium: a kinetic approach. Monatsh Chem 2010, 141, 1069. <https://doi.org/10.1007/s00706-010-0377-2>
  • Seregar Veeresh C., Hosamani Ragunatharaddi R., Nandibewoor Sharanappa T.: Investigation of the mechanism of oxidation of l-cystine by diperiodatoargentate(III) in aqueous alkaline medium by stopped flow technique. Transition Met Chem 2010, 35, 55. <https://doi.org/10.1007/s11243-009-9295-8>
  • Goel Anjali, Sharma Shivani: Mechanistic study of the oxidation of l-phenylalanine by hexacyanoferrate(III) catalyzed by iridium(III) in aqueous alkaline medium. Transition Met Chem 2010, 35, 549. <https://doi.org/10.1007/s11243-010-9362-1>
  • Malode Shweta J., Abbar Jyothi C., Nandibewoor Sharanappa T.: Mechanistic aspects of uncatalyzed and ruthenium(III) catalyzed oxidation of dl-ornithine monohydrochloride by silver(III) periodate complex in aqueous alkaline medium. Inorganica Chimica Acta 2010, 363, 2430. <https://doi.org/10.1016/j.ica.2010.03.081>
  • Deganatti Balesh A., Shetti Nagaraj P., Nandibewoor Sharanappa T.: Mechanistic investigations on the oxidation of l-valine by diperiodatocuprate(III) in aqueous alkaline medium: a kinetic model. Transition Met Chem 2009, 34, 143. <https://doi.org/10.1007/s11243-008-9170-z>
  • Hosamani R. R., Nandibewoor S. T.: Mechanistic study of ruthenium (III) catalysed oxidation of L-lysine by diperiodatoargentate (III) in aqueous alkaline medium. J Chem Sci 2009, 121, 275. <https://doi.org/10.1007/s12039-009-0030-y>
  • Hosamani R. R., Shetti N. P., Nandibewoor S. T.: A kinetic and mechanistic study on the oxidation of L-cystine by alkaline diperiodatocuprate(III): A free radical intervention. Kinet Catal 2009, 50, 530. <https://doi.org/10.1134/S0023158409040090>
  • Kulkarni Suresh D., Nandibewoor Sharanappa T.: Kinetics and mechanism of L-isoleucine oxidation by alkaline diperiodatoargentate(III). Transition Met Chem 2008, 33, 23. <https://doi.org/10.1007/s11243-007-9009-z>
  • Veeresh T.M., Nandibewoor Sharanappa T.: Thermodynamic quantities for the different steps involved in the mechanism of osmium(VIII) catalysed oxidation of l-lysine by a new oxidant, diperiodatoargentate(III) (stopped flow technique). The Journal of Chemical Thermodynamics 2008, 40, 284. <https://doi.org/10.1016/j.jct.2007.06.012>
  • Kushwaha N., Shukla R.K., Kumar A.: Observation of Meyer–Neldel rule in amorphous thin films of Se100−xSbx in presence of light. Journal of Non-Crystalline Solids 2006, 352, 5670. <https://doi.org/10.1016/j.jnoncrysol.2006.08.045>
  • Hiremath Chanabasayya V., Kulkarni Suresh D., Nandibewoor Sharanappa T.: Oxidation of l-Leucine by Alkaline Diperiodatoargentate(III) Deamination and Decarboxylation:  A Kinetic and Mechanistic Study. Ind. Eng. Chem. Res. 2006, 45, 8029. <https://doi.org/10.1021/ie060612d>
  • Yelon A, Movaghar B, Crandall R S: Multi-excitation entropy: its role in thermodynamics and kinetics. Rep. Prog. Phys. 2006, 69, 1145. <https://doi.org/10.1088/0034-4885/69/4/R04>
  • Baran?ok D., Kluv�nek P.: The Impact of the Meyer-Neldel Rule on the Non-Isothermal Observation of Thermally Stimulated Processes in Solids. phys. stat. sol. (a) 2002, 191, 339. <https://doi.org/10.1002/1521-396X(200205)191:1<339::AID-PSSA339>3.0.CO;2-B>
  • Farokhi Sairabanu A., Kini A.K., Nandibewoor S.T.: Oxidation of l -Hydroxyproline by Aqueous Alkaline Permanganate--A Kinetic Study. Inorganic Reaction Mechanisms 2002, 4, 67. <https://doi.org/10.1080/1028662021000003847>
  • Ouvrard Carole, Berthelot Michel, Laurence Christian: An enthalpic scale of hydrogen‐bond basicity, part 1: halogenoalkanes. J of Physical Organic Chem 2001, 14, 804. <https://doi.org/10.1002/poc.437>
  • Ouvrard Carole, Berthelot Michel, Lamer Thierry, Exner Otto: A Program for Linear Regression with a Common Point of Intersection:  The Isokinetic Relationship. J. Chem. Inf. Comput. Sci. 2001, 41, 1141. <https://doi.org/10.1021/ci000089s>
  • Liu Lei, Guo Qing-Xiang: Isokinetic Relationship, Isoequilibrium Relationship, and Enthalpy−Entropy Compensation. Chem. Rev. 2001, 101, 673. <https://doi.org/10.1021/cr990416z>
  • Alfaia António J. I., Calado António R. T., Reis João Carlos R.: Quaternization Reaction of Aromatic Heterocyclic Imines in Methanol − A Case of Strong Anti-Reactivity Selectivity Principle with Isoselective Temperature. Eur. J. Org. Chem. 2000, 2000, 3627. <https://doi.org/10.1002/1099-0690(200011)2000:21<3627::AID-EJOC3627>3.0.CO;2-J>
  • Eyler Gladys N., Cañizo Adriana I., Mateo Carmen M., Alvarez Elida E., Cafferata Lázaro F. R.: Solvent Effect in the Thermal Decomposition Reaction of trans-3,3-Dimethyl-5,6-tetramethylene-1,2,4-trioxacyclohexane. J. Org. Chem. 1999, 64, 8457. <https://doi.org/10.1021/jo980658j>
  • Lesnikovich A. I., Levchik G. F., Vorobéeva S. A.: Effect of the physical state of activators on the combustion of composite rocket propellants. II. Colloidal inhibitors. Combust Explos Shock Waves 1998, 34, 177. <https://doi.org/10.1007/BF02672818>
  • Fernandez Anthony, Reyes Clementina, Prock Alfred, Giering Warren P.: Exploring Ligand Effects through Isoequilibrium Phenomena:  The Quantitative Analysis of Ligand Effects. Organometallics 1998, 17, 2503. <https://doi.org/10.1021/om971041f>
  • Exner Otto: How to get wrong results from good experimental data: a survey of incorrect applications of regression. J. Phys. Org. Chem. 1997, 10, 797. <https://doi.org/10.1002/(SICI)1099-1395(199711)10:11<797::AID-PCA951>3.0.CO;2-K>
  • Zeman Svatopluk: Kinetic compensation effect and thermolysis mechanisms of organic polynitroso and polynitro compounds. Thermochimica Acta 1997, 290, 199. <https://doi.org/10.1016/S0040-6031(96)03078-X>
  • Galwey Andrew K.: Compensation behaviour recognized in literature reports of selected heterogeneous catalytic reactions: aspects of the comparative analyses and significance of published kinetic data. Thermochimica Acta 1997, 294, 205. <https://doi.org/10.1016/S0040-6031(96)03153-X>
  • Matha M., Sundari L. B. T., Rajanna K. C., Saiprakash P. K.: Kinetics and mechanism of hydrogen peroxide oxidation of chromone-3-carboxaldehydes in aqueous acid and micellar media. Int. J. Chem. Kinet. 1996, 28, 637. <https://doi.org/10.1002/kin.1>
  • Zsakó J.: Compensation effect in heterogeneous non-isothermal kinetics. Journal of Thermal Analysis 1996, 47, 1679. <https://doi.org/10.1007/BF01980913>
  • TüdŐs F., Dávid P. K.: Comments on the interpretation of temperature dependence of processes in polymers. Journal of Thermal Analysis 1996, 47, 589. <https://doi.org/10.1007/BF01984000>
  • Rajanna K.C, Solomon Florence, Ali Mir Moazzam, Saiprakash P.K: Kinetics and mechanism of Vilsmeier-Haack synthesis of 3-formyl chromones derived from o-hydroxy aryl alkyl ketones: A structure reactivity study. Tetrahedron 1996, 52, 3669. <https://doi.org/10.1016/0040-4020(96)00043-9>
  • Teyssèdre G., Demont P., Lacabanne C.: Analysis of the experimental distribution of relaxation times around the liquid–glass transition of poly(vinylidene fluoride). Journal of Applied Physics 1996, 79, 9258. <https://doi.org/10.1063/1.362601>
  • Teyssedre G., Bernes A., Lacabanne C.: Cooperative movements associated with the Curie transition in P(VDF‐TrFE) copolymers. J Polym Sci B Polym Phys 1995, 33, 879. <https://doi.org/10.1002/polb.1995.090330603>
  • Zeman Svatopluk: New application of kinetic data of the low-temperature thermolysis of nitroparaffins. Thermochimica Acta 1995, 261, 195. <https://doi.org/10.1016/0040-6031(95)02325-V>
  • Teyssedre G, Lacabanne C: Some considerations about the analysis of thermostimulated depolarization peaks. J. Phys. D: Appl. Phys. 1995, 28, 1478. <https://doi.org/10.1088/0022-3727/28/7/029>
  • Bell Julie L.S., Palmer Donald A., Barnes H.L., Drummond S.E.: Thermal decomposition of acetate: III. Catalysis by mineral surfaces. Geochimica et Cosmochimica Acta 1994, 58, 4155. <https://doi.org/10.1016/0016-7037(94)90271-2>
  • Koga Nobuyoshi: A review of the mutual dependence of Arrhenius parameters evaluated by the thermoanalytical study of solid-state reactions: The kinetic compensation effect. Thermochimica Acta 1994, 244, 1. <https://doi.org/10.1016/0040-6031(94)80202-5>
  • Hodgkin J H, Jackson M B, Morton T C: High Perform. Polym. 1994, 6, 437. <https://doi.org/10.1088/0954-0083/6/4/011>
  • Zeman Svatopluk: New dependence of Activation Energies of Nitroesters Thermolysis and possibility of its application. Propellants Explo Pyrotec 1992, 17, 17. <https://doi.org/10.1002/prep.19920170106>
  • Ostrovskii V. A., Poplavskii V. S., Koldobskii G. I., Erusalimskii G. B.: Tetrazoles. 31. Kinetics of the reaction of nitriles with alkylammonium azides. Formation of 5-substituted tetrazoles. Chem Heterocycl Compd 1992, 28, 1027. <https://doi.org/10.1007/BF00531480>
  • Yelon A., Movaghar B., Branz H. M.: Origin and consequences of the compensation (Meyer-Neldel) law. Phys. Rev. B 1992, 46, 12244. <https://doi.org/10.1103/PhysRevB.46.12244>
  • Babu N Vijaya, Rajanna K C, Ram Rao C Janaki: Synthesis and characterisation of 1-methacroyl 3-salicyloyl 2-hydroxy propane and its derivatives—A structure-reactivity kinetic study. Proc. Indian Acad. Sci. (Chem. Sci.) 1991, 103, 549. <https://doi.org/10.1007/BF02874653>
  • Koga Nobuyoshi, Šesták Jaroslav: Kinetic compensation effect as a mathematical consequence of the exponential rate constant. Thermochimica Acta 1991, 182, 201. <https://doi.org/10.1016/0040-6031(91)80005-4>
  • Budrugeac P., Ciutacu S.: Thermal degradation of polychloroprene rubber. Polymer Degradation and Stability 1991, 33, 377. <https://doi.org/10.1016/0141-3910(91)90083-4>
  • Zeman Svatopluk, Dimun Milan: On the study of micromechanism governing Detonation Initiation of Nitramines and Nitrosamines. Propellants Explo Pyrotec 1990, 15, 217. <https://doi.org/10.1002/prep.19900150508>
  • Agrawal Ravindra K.: The compensation effect. Journal of Thermal Analysis 1988, 34, 1141. <https://doi.org/10.1007/BF01913517>
  • Rao Ch. Nagarjun, Rajanna K. C., Devi Y. Uma, Rao V. Surender, Saiprakash P. K.: Thermodynamic parameters and stability constants of some tervalent lanthanide complexes of 1-(3-aryl-5-hydroxy 4-isoxazolylazo) 4-sulphonic acids. Proc. Indian Acad. Sci. (Chem. Sci.) 1988, 100, 329. <https://doi.org/10.1007/BF02840543>
  • Banerji Kalyan K.: Mechanism of the oxidation of organic sulphides by permanganate ion. Tetrahedron 1988, 44, 2969. <https://doi.org/10.1016/S0040-4020(88)90035-X>
  • del Val J. J., Lacabanne C., Hiltner A.: A thermostimulated creep study of blends of poly(vinyl chloride) and chlorinated polyethylene. Journal of Applied Physics 1988, 63, 5312. <https://doi.org/10.1063/1.340395>
  • Zsakó J., Somasekharan K. N.: Critical remarks on “On the compensation effect”. Journal of Thermal Analysis 1987, 32, 1277. <https://doi.org/10.1007/BF01905182>
  • Lewis Nita A., Ray Amanda M.: Solvent effects on redox reactions. 2. The Cr(II) reduction of tris(pentane-2,4-dionato)cobalt(lII) in water/acetone solvent mixtures. Inorganica Chimica Acta 1987, 132, 49. <https://doi.org/10.1016/S0020-1693(00)83989-4>
  • Agrawal Ravindra K.: On the compensation effect. Journal of Thermal Analysis 1986, 31, 73. <https://doi.org/10.1007/BF01913888>
  • Lesnikovich A. I., Levchik S. V.: Isoparametric kinetic relations for chemical transformations in condensed substances (analytical survey). I. Journal of Thermal Analysis 1985, 30, 237. <https://doi.org/10.1007/BF02128134>
  • Gupta V.K.: Thermodynamic and related studies for the oxidation of sulpha drugs by the peroxydisulphate ion. Thermochimica Acta 1983, 69, 389. <https://doi.org/10.1016/0040-6031(83)80346-3>
  • Schmid R., Han L.: Novel mechanistic aspects of the reduction of iron(III) phenanthroline complexes by aquo iron(II). Temperature dependence of the substituent effect. Inorganica Chimica Acta 1983, 69, 127. <https://doi.org/10.1016/S0020-1693(00)83562-8>
  • Barandiarán J. M., Del Val J. J., Colmenero J., Lacabanne C., Chatain D., Millán J., Martínez G.: Thermally stimulated currents in poly(vinyl chloride): Tacticity and molecular weight influence. Journal of Macromolecular Science, Part B 1983, 22, 645. <https://doi.org/10.1080/00222348308245748>
  • Srinivasan C., Pitchumani K.: Mechanism of oxidation of phenylthioacetic acids by potassium peroxodiphosphate. Int J of Chemical Kinetics 1982, 14, 789. <https://doi.org/10.1002/kin.550140707>
  • Sircar A., Mallik B., Misra T. N.: Compensation Effect in the Electrical Conduction Process in a Series of Naphthyl Polyenes. phys. stat. sol. (a) 1982, 69, 767. <https://doi.org/10.1002/pssa.2210690241>
  • Linert W., Soukup R.W., Schmid R.: Statistical analysis of the isokinetic relationship using a programmable calculator. Computers & Chemistry 1982, 6, 47. <https://doi.org/10.1016/0097-8485(82)80010-7>
  • Worstell Jonathan H., Daniel Stephen R.: Deposit formation in liquid fuels. 2. The effect of selected compounds on the storage stability of Jet A turbine fuel. Fuel 1981, 60, 481. <https://doi.org/10.1016/0016-2361(81)90108-3>
  • Mallik B., Ghosh A., Misra T. N.: Compensation effect in the electrical conduction process in some polyene semiconductors. Phys. Stat. Sol. (a) 1980, 62, 267. <https://doi.org/10.1002/pssa.2210620131>
  • Chornet E., Roy C.: Compensation effect in the thermal decomposition of cellulosic materials. Thermochimica Acta 1980, 35, 389. <https://doi.org/10.1016/0040-6031(80)87140-1>
  • Lemière G. L., van Osselaer T. A., Alderweireldt F. C.: Additional Evidence for the Existence of Only One Kind of Transition State in the NABH4 Reduction of Aliphatic Ketones. Bulletin des Soc Chimique 1978, 87, 771. <https://doi.org/10.1002/bscb.19780871006>
  • KRUG R. R., HUNTER W. G., GRIEGER R. A.: Statistical interpretation of enthalpy–entropy compensation. Nature 1976, 261, 566. <https://doi.org/10.1038/261566a0>
  • Müller Paul, Perlberger Jean‐Claude: Isokinetic Relationships in Alcohol Oxidation with Chromic Acid. Helvetica Chimica Acta 1974, 57, 1943. <https://doi.org/10.1002/hlca.19740570707>
  • Chatain D., Gautier P., Lacabanne C.: Ionic thermal current study of the α′ process in poly(hexamethylene adipamide). J. Polym. Sci. Polym. Phys. Ed. 1973, 11, 1631. <https://doi.org/10.1002/pol.1973.180110811>
  • Chatain D., Lacabanne C., Maitrot M., Seytre G., May J. F.: Depolarization thermocurrents of polyglycine I and II. Phys. Stat. Sol. (a) 1973, 16, 225. <https://doi.org/10.1002/pssa.2210160124>
  • Rosenberg Barnett, Kemeny Gabor, Smith Lawrence G., Skurnick Ira D., Bandurski Mary J.: The kinetics and thermodynamics of death in multicellular organisms. Mechanisms of Ageing and Development 1973, 2, 275. <https://doi.org/10.1016/0047-6374(73)90023-7>
  • KEMENY GABOR, ROSENBERG BARNETT: Compensation Law in Thermodynamics and Thermal Death. Nature 1973, 243, 400. <https://doi.org/10.1038/243400a0>
  • EXNER O.: ChemInform Abstract: STATISTIK DER ENTHALPIE‐ENTROPIE‐BEZIEHUNG 1. MITT. DER SPEZIELLE FALL. Chemischer Informationsdienst 1972, 3. <https://doi.org/10.1002/chin.197234094>