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Collect. Czech. Chem. Commun. 1970, 35, 339-343
https://doi.org/10.1135/cccc19700339

Chemistry of boranes. XVIII. A preparative separation of halogenodecaboranes. The isolation of 1-, 2-, 5-, and 6-bromotridecahydrodecaboranes

J. Stuchlík, S. Heřmánek, J. Plešek and B. Štíbr

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  • Sivaev Igor B.: Decaborane: From Alfred Stock and Rocket Fuel Projects to Nowadays. Molecules 2023, 28, 6287. <https://doi.org/10.3390/molecules28176287>
  • Štíbr Bohumil: Alpha shift correlation (ASC) method. Sensitivity of 11B NMR shifts to halogen substitution in the ten-vertex nido and arachno series of boron clusters. Linear behavior of NMR effects. Inorganica Chimica Acta 2018, 471, 615. <https://doi.org/10.1016/j.ica.2017.11.040>
  • Chatterjee Shahana, Carroll Patrick J., Sneddon Larry G.: Iridium and Ruthenium Catalyzed Syntheses, Hydroborations, and Metathesis Reactions of Alkenyl-Decaboranes. Inorg. Chem. 2013, 52, 9119. <https://doi.org/10.1021/ic401356u>
  • Ewing William C., Carroll Patrick J., Sneddon Larry G.: Syntheses and Surprising Regioselectivity of 5- and 6-Substituted Decaboranyl Ethers via the Nucleophilic Attack of Alcohols on 6- and 5-Halodecaboranes. Inorg. Chem. 2011, 50, 4054. <https://doi.org/10.1021/ic102544v>
  • Ewing William C., Carroll Patrick J., Sneddon Larry G.: Efficient Syntheses of 5-X-B10H13 Halodecaboranes via the Photochemical (X = I) and/or Base-Catalyzed (X = Cl, Br, I) Isomerization Reactions of 6-X-B10H13. Inorg. Chem. 2010, 49, 1983. <https://doi.org/10.1021/ic9024487>
  • Ewing William C., Carroll Patrick J., Sneddon Larry G.: Crystallographic Characterizations and New High-Yield Synthetic Routes for the Complete Series of 6-X-B10H13 Halodecaboranes (X = F, Cl, Br, I) via Superacid-Induced Cage-Opening Reactions of closo-B10H102−. Inorg. Chem. 2008, 47, 8580. <https://doi.org/10.1021/ic801288e>
  • Stuchlík Jiřf: Gas chromatographic separation of 1- and 2-halogenodecaboranes. Journal of Chromatography A 1973, 81, 142. <https://doi.org/10.1016/S0021-9673(01)82326-8>