Collect. Czech. Chem. Commun. 1968, 33, 1143-1156
https://doi.org/10.1135/cccc19681143

Syntheses with anhydro sugars. V. Preparation of 2,4-di-O-substituted 1,6-anhydro-β-D-hexopyranos-3-uloses and their isomerization and reduction

M. Černý, L. Kalvoda and J. Pacák

Individual author index pages


Other CCCC articles of these authors

  • M. Černý
    Synthesis of an optically active silylated diphosphine and related dinitrile derived from L-(+)-tartaric acid
    1977, Vol. 42, Issue 10, pp. 3069–3078 [Abstract]
  • J. Pacák, M. Braunová, D. Štropová and M. Černý
    Fluorinated derivatives of 1,6-anhydro-β-D-ribo-hexopyranos-3-ulose
    1977, Vol. 42, Issue 1, pp. 120–131 [Abstract]
  • K. Horská, L. Kalvoda and K. Šebesta
    Inhibition of DNA-dependent RNA polymerase by derivatives and analogues of thuringiensin
    1976, Vol. 41, Issue 12, pp. 3837–3841 [Abstract]
  • M. Černý, I. Černý and J. Pacák
    Preparation of 4-amino-1,6-anhydro-4-deoxy-β-D-glucopyranose. Isomerization of 4-amino-1,6 : 2,3-dianhydro-4-deoxy-β-D-mannopyranose to 1,6-anhydro-3,4-dideoxy-3,4-epimino-β-D-altropyranose
    1976, Vol. 41, Issue 10, pp. 2942–2951 [Abstract]
  • L. Kalvoda
    Synthesis of ethyl 3-cyano-2-alkenoates by the Wittig condensation and their use in the preparation of 2-substituted maleinimides
    1976, Vol. 41, Issue 7, pp. 2034–2039 [Abstract]
  • J. Doležalová, M. Černý, T. Trnka and J. Pacák
    Preparation of 1,6-anhydro derivatives of 2,4-dideoxy-2-fluoro-β-D-xylo-hexopyranose and 2,3-dideoxy-2-fluoro-β-D-ribo-hexopyranose and corresponding reducing sugars
    1976, Vol. 41, Issue 7, pp. 1944–1953 [Abstract]
  • M. Prystaš, L. Kalvoda and F. Šorm
    Alternative synthesis of exotoxin from Bacillus thuringiensis
    1976, Vol. 41, Issue 5, pp. 1426–1447 [Abstract]
  • L. Kalvoda, M. Prystaš and F. Šorm
    Synthesis of exotoxin produced by Bacillus thuringiensis. II. Formation of the α-glucosidic bond, nucleosidation, phosphorylation
    1976, Vol. 41, Issue 3, pp. 800–815 [Abstract]
  • L. Kalvoda, M. Prystaš and F. Šorm
    Synthesis of exotoxin produced by Bacillus thuringiensis. I. Formation of the ethereal bond between ribose and glucose
    1976, Vol. 41, Issue 3, pp. 788–799 [Abstract]
  • J. Schraml, J. Pola, H. Jancke, G. Engelhardt, M. Černý and V. Chvalovský
    Application of 29Si-NMR to analysis of silylated compounds. NMR spectra of (CH3)3Si-O-C derivatives
    1976, Vol. 41, Issue 2, pp. 360–367 [Abstract]
  • M. Černý and J. Málek
    Methylation and ethylation of the aryl-activated benzylic group and formation of gem-diarylcyclopropanes by means of bis(2-alkoxyethoxy)aluminium hydrides
    1976, Vol. 41, Issue 1, pp. 119–130 [Abstract]
  • M. Černý
    Preparation and properties of some o-, m-, and p-phenoxyarylsiloxanes
    1976, Vol. 41, Issue 1, pp. 114–118 [Abstract]
  • M. Černý
    Preparation of diphenylalkoxychlorosilanes and diphenyldialkoxysilanes
    1976, Vol. 41, Issue 1, pp. 110–113 [Abstract]
  • T. Trnka, M. Černý, M. Buděšínský and J. Pacák
    The synthesis of 3-amino-3-deoxy-D-glucose (kanosamine) and its 1,6-anhydro derivative conformation of amino derivatives of 1,6-anhydro-β-D-hexopyranoses
    1975, Vol. 40, Issue 10, pp. 3038–3045 [Abstract]
  • Azza Amin Ahmed El-Attar and M. Černý
    The preparation and thermal behaviour of some polyarylsilanes
    1975, Vol. 40, Issue 9, pp. 2806–2815 [Abstract]
  • M. Černý
    The preparation and properties of some phenoxyarylsilanes
    1975, Vol. 40, Issue 9, pp. 2642–2648 [Abstract]
  • M. Černý, O. Juláková, J. Pacák and M. Buděšínský
    Isomerization of 2-amino-1,6 : 3,4-dianhydro-2-deoxy-β-D-galactopyranose to 1,6-anhydro-2,3-dideoxy-2,3-epimino-β-D-gulopyranose in alkaline medium
    1975, Vol. 40, Issue 7, pp. 2116–2119 [Abstract]
  • M. Prystaš, L. Kalvoda and F. Šorm
    Structure proof of exotoxin from Bacillus thuringiensis
    1975, Vol. 40, Issue 6, pp. 1775–1785 [Abstract]
  • J. Frgala, M. Černý and J. Staněk, jr
    Preparation of alkyl 1-thio-β-D-galactopyranosides substituted in the alkyl with reactive groups
    1975, Vol. 40, Issue 5, pp. 1411–1425 [Abstract]
  • J. Pacák, J. Hriňák and M. Černý
    The synthesis of 6-amino-2,6-dideoxy-2-fluoro-D-glucose
    1974, Vol. 39, Issue 11, pp. 3332–3337 [Abstract]
  • J. Málek, M. Černý and R. Řeřicha
    Formation of anionic intermediates in the reduction and alkylation of anthracene and its derivatives by sodium bis(2-methoxyethoxy)aluminum hydride
    1974, Vol. 39, Issue 9, pp. 2656–2666 [Abstract]
  • M. Černý, M. Kollmann, J. Pacák and M. Buděšínský
    Preparation of branched-chain hexoses by reaction of 1,6-anhydro-2,4-di-O-p-toluenesulfonyl-β-D-hexopyranos-3-uloses with Grignard reagents
    1974, Vol. 39, Issue 9, pp. 2507–2519 [Abstract]
  • V. Bažant and M. Černý
    Synthesis of p-chlorophenyldiphenylsilanes and unsymmetrical p-bis-silylarylenes from p-dichlorobenzene and p-bromochlorobenzene by the Grignard reaction
    1974, Vol. 39, Issue 7, pp. 1880–1884 [Abstract]
  • M. Černý, T. Elbert and J. Pacák
    Preparation of 1,6-anhydro-2,3-dideoxy-2,3-epimino-β-D-mannopyranose and its conversion to 2-amino-1,6-anhydro-2-deoxy-β-D-mannopyranose
    1974, Vol. 39, Issue 7, pp. 1752–1767 [Abstract]
  • V. Bažant and M. Černý
    Synthesis of p-bis-silylarylene compounds by the Grignard reaction of p-dibromobenzene with dialkoxy-, dichloro-, alkoxychloro- and chlorodiphenylsilanes
    1974, Vol. 39, Issue 7, pp. 1735–1739 [Abstract]
  • V. Bažant and M. Černý
    Synthesis of p-bis-silylarylene compounds by the Grignard reaction of p-dichlorobenzene with dialkoxy-, dichloro-, alkoxychloro- and chlorodiphenylsilanes
    1974, Vol. 39, Issue 7, pp. 1728–1734 [Abstract]
  • M. Černý, O. Juláková and J. Pacák
    Preparation of 2-amino-1,6-anhydro-2-deoxy-β-D-glucopyranose and 2-amino-1,6:3,4-dianhydro-2-deoxy-β-D-galactopyranose
    1974, Vol. 39, Issue 5, pp. 1391–1396 [Abstract]
  • J. Pecka, J. Staněk, jr and M. Černý
    Preparation and the properties of 2,3-, 2,4-, and 3,4-dideoxy derivatives of 1,6-anhydro-β-D-glycero-hexopyranosuloses and corresponding alcohols
    1974, Vol. 39, Issue 5, pp. 1192–1209 [Abstract]
  • M. Černý and J. Málek
    Simultaneous hydrogenolysis and alkylation of aromatic ketones by sodium bis(2-methoxyethoxy)aluminum hydride at elevated temperatures
    1974, Vol. 39, Issue 3, pp. 842–853 [Abstract]
  • J. Pacák, P. Drašar, D. Štropová, M. Černý and M. Buděšínský
    Syntheses with anhydro sugars. XVIII. Aminodideoxyfluorine derivatives of D-glucose
    1973, Vol. 38, Issue 12, pp. 3936–3939 [Abstract]
  • J. Nývlt, H. Kočová and M. Černý
    Size distribution of crystals from a batch crystallizer
    1973, Vol. 38, Issue 11, pp. 3199–3209 [Abstract]
  • L. Kalvoda, M. Prystaš and F. Šorm
    Nucleic acid components and their analogues. CLX. Determination of the structure of the allaric portion of exotoxin from Bacillus thuringiensis by means of periodate oxidation
    1973, Vol. 38, Issue 8, pp. 2529–2532 [Abstract]
  • J. Halbych, T. Trnka and M. Černý
    Syntheses with anhydro sugars. XVII. Preparation and reactions of 1,6:2,3-dianhydro-4-deoxy- and 1,6:3,4-dianhydro-2-deoxy-β-D-hexopyranoses with nucleophilic and reducing reagents
    1973, Vol. 38, Issue 7, pp. 2151–2166 [Abstract]
  • J. Šmejkal and L. Kalvoda
    Ruthenium tetraoxide oxidation of the primary hydroxylic function to the carboxyl in sugar derivatives (Preparation of uronic acids)
    1973, Vol. 38, Issue 7, pp. 1981–1984 [Abstract]
  • L. Kalvoda
    Acid-catalysed C-ribofuranosylation of benzene derivatives; Some novel conversions of C-ribofuranosyl derivatives
    1973, Vol. 38, Issue 6, pp. 1679–1692 [Abstract]
  • J. Pacák, P. Drašar, J. Nerudová and M. Černý
    Syntheses with anhydro sugars. XIV. Synthesis of some derivatives of 1,6-anhydro-4-deoxy-4-fluoro-β-D-glucopyranose
    1972, Vol. 37, Issue 12, pp. 4120–4125 [Abstract]
  • L. Kalvoda
    Oxidative degradation of 1,4-benzoquinone amino and hydroxy derivatives into maleic and fumaric acids
    1972, Vol. 37, Issue 12, pp. 4046–4049 [Abstract]
  • J. Pacák, J. Halásková, V. Štěpán and M. Černý
    Synthesis of 1,6-dideoxy-1,6-difluoro-D-fructose
    1972, Vol. 37, Issue 11, pp. 3646–3651 [Abstract]
  • T. Trnka and M. Černý
    Syntheses with anhydro sugars. XIII. Preparation of the deoxy derivatives of the 1,6-anhydro-β-D-hexopyranoses by catalytic reduction of 1,6:2,3- and 1,6:3,4-dianhydro-β-D-hexopyranoses
    1972, Vol. 37, Issue 11, pp. 3632–3639 [Abstract]
  • M. Černý, V. Přikrylová and J. Pacák
    Syntheses with anhydro sugars. XII. Preparation of 2,6-dideoxy-2-fluoro-D-glucose
    1972, Vol. 37, Issue 9, pp. 2978–2984 [Abstract]
  • J. Pacák, J. Podešva, Z. Točík and M. Černý
    Syntheses with anhydro sugars. XI. Preparation of 2-deoxy-2-fluoro-D-glucose and 2,4-dideoxy-2,4-difluoro-D-glucose
    1972, Vol. 37, Issue 8, pp. 2589–2599 [Abstract]
  • I. Sláma and J. Pacák
    Catalytic oxidation of hydrogen chloride with oxygen in melts of copper chlorides
    1971, Vol. 36, Issue 12, pp. 4021–4025 [Abstract]
  • M. Černý and J. Málek
    Properties of sodium bis(2-methoxyethoxy)aluminium hydride. XII. Reduction and hydrogenolysis of sodium and bromomagnesium salts of some aliphatic and aromatic carboxylic acids
    1971, Vol. 36, Issue 6, pp. 2394–2397 [Abstract]
  • T. Trnka and M. Černý
    Syntheses with anhydro sugars. X. Cleavage of oxiran ring in 1,6:2,3- and 1,6:3,4-dianhydro-β-D-hexopyranoses with potassium hydroxide and sulfuric acid
    1971, Vol. 36, Issue 6, pp. 2216–2225 [Abstract]
  • M. Černý and J. Málek
    Properties of sodium bis(2-methoxyethoxy)aluminium hydride. XI. Reduction and hydrogenolysis of hydroxy-substituted aldehydes, ketones, carboxylic acids and carbinols of the naphthalene series
    1970, Vol. 35, Issue 10, pp. 3079–3084 [Abstract]
  • M. Černý and J. Málek
    Über die Eigenschaften von Natrium-bis-(2-methoxyäthoxy)aluminiumhydrid X. Reduktion und Hydrogenolyse einiger hydroxy- und alkoxysubstituierten aromatischen Carbinole, Aldehyde, Ketone, Carbonsäuren und ihrer Derivate
    1970, Vol. 35, Issue 7, pp. 2030–2043 [Abstract]
  • M. Černý and J. Málek
    Properties of sodium bis(2-methoxyethoxy)aluminium hydride. IX. Reduction and hydrogenolysis of amino-substituted aromatic aldehydes, ketones, carboxylic acids, esters, and carbinols
    1970, Vol. 35, Issue 4, pp. 1216–1223 [Abstract]
  • M. Černý, T. Trnka, P. Beran and J. Pacák
    Syntheses with anhydro sugars. VIII. Preparation of 1,6:2,3-dianhydro- and 1,6:3,4-dianhydro-β-D-allopyranose
    1969, Vol. 34, Issue 11, pp. 3377–3382 [Abstract]
  • M. Černý, J. Staněk, Jr. and J. Pacák
    Syntheses with anhydrosugars. VII. Preparation of 4-deoxy-D-ribo-hexose (4-deoxy-D-allose), 4-deoxy-D-lyxo-hexose (4-deoxy-D-mannose) and of their 1,6-anhydro derivatives
    1969, Vol. 34, Issue 6, pp. 1750–1765 [Abstract]
  • M. Černý, J. Málek, M. Čapka and V. Chvalovský
    Properties of sodium bis-(2-methoxyethoxy)aluminium hydride. IV. Reduction of oximes, amides, lactams, imides and nitriles
    1969, Vol. 34, Issue 3, pp. 1033–1041 [Abstract]
  • M. Černý, J. Málek, M. Čapka and V. Chvalovský
    Properties of sodium bis-(2-methoxyethoxy)aluminium hydride. III. Reduction of carboxylic acids and their derivatives
    1969, Vol. 34, Issue 3, pp. 1025–1032 [Abstract]
  • M. Černý, J. Staněk, Jr. and J. Pacák
    Syntheses with anhydro sugars. VI. The reactivity of p-toluenesulfonyl esters of 1,6-anhydro-β-D-glucopyranose during the formation of epoxy derivatives in alkaline medium
    1969, Vol. 34, Issue 3, pp. 849–856 [Abstract]
  • J. Staněk, M. Šindlerová, O. Hánová, M. Černý and J. Pacák
    Synthese nichtreduzierender Thiodisaccharide
    1965, Vol. 30, Issue 7, pp. 2494–2497 [Abstract]
  • M. Černý, J. Pacák and J. Staněk
    Synthesen mit Anhydrozuckern IV. Darstellung von 1,6-2,3-Dianhydro-β-D-mannopyranose und ihre Isomerisierung zu 1,6-3,4-Dianhydro-β-D-altropyranose
    1965, Vol. 30, Issue 4, pp. 1151–1157 [Abstract]
  • J. Staněk, M. Šindlerová and M. Černý
    Derivatives of D-thioxylopyranose and of some reducing 1-deoxy-1-thiodisaccharides
    1965, Vol. 30, Issue 1, pp. 297–303 [Abstract]
  • M. Černý, I. Buben and J. Pacák
    Synthesen mit Anhydrozuckern III. Über die Reaktion von 2-O-Tosyl-1,6:3,4-dianhydro-β-D-galaktopyranose mit Natriumhydroxyd
    1963, Vol. 28, Issue 6, pp. 1569–1578 [Abstract]
  • J. Pacák and M. Černý
    Darstellung und Strukturnachweis von 4,6-O-Benzyliden-D-galaktopyranose
    1963, Vol. 28, Issue 2, pp. 541–544 [Abstract]
  • M. Černý and J. Pacák
    Desoxyzucker III. Über Reaktionen der 2-O-Tosyl-1,6:3,4-dianhydro-β-D-galaktopyranose Darstellung von 4-Desoxy-D-xylohexose (4-Desoxy-D-glucose) und 4-Desoxy-D-arabinohexose (4-Desoxy-D-altrose)
    1962, Vol. 27, Issue 1, pp. 94–105 [Abstract]
  • R. Lukeš and M. Černý
    Reaktion des Allylmagnesiumbromids mit O-Methylvalerolactim
    1961, Vol. 26, Issue 11, pp. 2886–2890 [Abstract]
  • M. Černý, V. Gut and J. Pacák
    Partielle Substitution der 1,6-Anhydro-β-D-glucopyranose
    1961, Vol. 26, Issue 10, pp. 2542–2550 [Abstract]
  • J. Pacák and M. Černý
    1,2:3,4-Di-O-benzyliden-D-galaktopyranose
    1961, Vol. 26, Issue 9, pp. 2212–2216 [Abstract]
  • M. Černý, D. Zachystalová and J. Pacák
    Darstellung acetylierter aromatischer β-D-Thioglucopyranoside durch Reaktion von Diazoniumsalzen mit 2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosylmercaptan
    1961, Vol. 26, Issue 9, pp. 2206–2211 [Abstract]
  • M. Černý and J. Pacák
    Darstellung von 2,3,4,6-Tetra-O-acetyl-β-D-glucopyranosylmercaptan und von Natrium- und Gold-β-D-glucopyranosylmercaptid
    1961, Vol. 26, Issue 8, pp. 2084–2086 [Abstract]
  • J. Pacák and M. Černý
    Kondensation von Sacchariden mit Carbonylverbindungen in Gegenwart von Metaphosphorsäureäthylester
    1959, Vol. 24, Issue 11, pp. 3804–3807 [Abstract]
  • R. Lukeš and M. Černý
    Einwirkung des Grignard-Reagenz auf die Amidgruppe XXV. Darstellung von 1-Methyl-2-allylpiperidin
    1959, Vol. 24, Issue 11, pp. 3596–3600 [Abstract]
  • R. Lukeš and M. Černý
    Über die Einwirkung des Grignard-Reagenz auf die Amidgruppe XXV. Über die Reaktion von Allylmagnesiumbromid mit Glutarsäuremethylimid
    1959, Vol. 24, Issue 8, pp. 2722–2726 [Abstract]
  • M. Černý and J. Pacák
    Eine neue Methode zur Darstellung acetylierter β-D-Thioglucopyranoside
    1959, Vol. 24, Issue 8, pp. 2566–2570 [Abstract]
  • R. Lukeš and M. Černý
    Ein neues Darstellungsverfahren für 1-Methyl-2-alkylpiperidine
    1959, Vol. 24, Issue 4, pp. 1287–1290 [Abstract]
  • J. Staněk and M. Černý
    Zur Bildung von Acetylderivaten der Glykosylamine
    1959, Vol. 24, Issue 3, pp. 1017–1019 [Abstract]
  • M. Černý, J. Vrkoč and J. Staněk
    Über die Darstellung von acylierten Derivaten der Glucopyranosylmercaptane
    1959, Vol. 24, Issue 1, pp. 64–69 [Abstract]
  • R. Lukeš and M. Černý
    Über die Einwirkung von Grignard-Reagenz auf die Amidgruppe XX. Die Reaktion von Vinylmagnesiumbromid mit Glutarsäuremethylimid
    1958, Vol. 23, Issue 5, pp. 946–953 [Abstract]
  • R. Lukeš and M. Černý
    Über die Einwirkung des Grignard-Reagenz auf die Amidgruppe XIX. Darstellung von einigen höheren 4-Ketosäuren
    1958, Vol. 23, Issue 3, pp. 497–503 [Abstract]
  • J. Pacák and M. Černý
    Anwendung von Metaphosphorsäure-äthylester zur Darstellung von Isopropylidenderivaten unsubstituierter Monosaccharide
    1958, Vol. 23, Issue 3, pp. 490–496 [Abstract]
  • M. Černý and J. Pacák
    Desoxysugars. II. Preparation of 3-desoxy-D-glucose and some of its derivatives
    1956, Vol. 21, Issue 4, pp. 1003–1006 [Abstract]
  • V. Horák and J. Pacák
    Thiophan derivatives. II. The synthesis and spontaneous decomposition of 2,5-bis-bromacetylthiophan
    1953, Vol. 18, Issue 3, pp. 384–387 [Abstract]
  • V. Horák and M. Černý
    Eine neue Methode zur Darstellung von Penthianonen
    1953, Vol. 18, Issue 3, pp. 379–383 [Abstract]